U of M Researchers Create First Bionic Particle

Submitted by Edward Khil on

http://www.salon.com/2014/05/22/scientists_create_bionic_particles_inspired_by_terminator/

Bionic particles combining proteins and semiconductors, with the goal of deriving fuel from sunlight using photosynthesis.

According to the University of Michigan, the particles 'blend the strengths of inorganic materials, which can readily convert light energy to electron energy, with biological molecules whose chemical functions have been highly developed through evolution.'

To be fair, University of Pittsburgh researchers got equal credit in the article, which also links to umich.edu.

 

Michigan Manders

May 22nd, 2014 at 9:12 PM ^

First off, I'm not a huge fan of that article. Instead, the OP should link to the umich article. It's much less sensationalist and contains more of the actual science.

I also want to clear up that cytochrome c is not actually a molecule involved in photosynthesis. Rather, it is an electron carrier in cellular respiration. Minor difference, but it makes me nervous about the validity of the rest of the article.

Anyway... this is mostly just a step in the right direction. From what I gather, the paper doesn't really claim to have created an important application for this yet. This is just the basis for future development, which could take quite awhile. What they've done is figured out a mechanism to create self assembling complexes of biological molecules and inorganic (created) materials (in this case, a semi conductor).

In their experiment they were able to make these complexes convert nitrate (NO3-) to nitrite (NO2-) and O2. Nitrate is toxic at high levels in water, but in most circumstances it never gets high enough (it usually happens on farms near lakes/rivers where too much fertilizer was used). The problem they ran into is that this process eventually degraded the complexes enough to where they didn't work any longer, something they can work on fixing.

What I imagine the process these partiles use is something like:

sunlight excites electrons in semi conductors -> electron transferred to cytochrome c (a soluble electron carrier) -> electrons used in other enzymatic processes that convert nitrate to nitrite.

 

Using this for carbon fixation is a whole nother animal. It warrants future study, but we're still a long ways away from that.

imMaizeNBlu

May 22nd, 2014 at 8:54 PM ^

Basically we can get a renewable energy resource that is plentiful, eco-friendly, easy accessible to the masses, and can hopefully replace fracking in producing natural gas for consumer consumption I believe. Exciting stuff and hopefully it shows progress in development.

TruBluMich

May 22nd, 2014 at 10:44 PM ^

Ok, someone want to explain this in a way that let's us know what level of excitement we should have?

Is this on the same level as the earth is round or is it more like they figured out how to get cheese in the crust of a pizza?

Meson

May 22nd, 2014 at 11:31 PM ^

Speaking as a graduate student in the ChemE department (but not in Kotov or Glotzer's groups), the actual researchers/professors don't have much control over the press release. The carbon dioxide part was probably mentioned as a 'eventually, we hope to do this decades down the road' and was played up in the article. They'd likely have to use completely different enzymes and semiconductors to do that, as carbon dioxide requires a LOT of energy to turn into something useful.
 
Kotov mentioning the Terminator is playing to the media and it doesn't really describe what they've done. At all. They use cadmium telluride (inorganic) to generate an excited electron that they shuttle to a protein/enzymes (biological) to do chemistry. It's pretty neat because enzymes are typically efficient but the applications might be limited - biological processes/enzymes are (relatively) slow compared to non-biological.